Define heat of fusion.Define heat of solidification.Perform calculations of energy changes during the transition from solid to liquid or liquid to solid.

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What makes the ice melt?

Suppose you hold an ice cube in your hand. It feels cold because heat energy leaves your hand and enters the ice cube. What happens to the ice cube? It melts. However, the temperature during a phase change remains constant. So the heat that is being lost by your hand does not raise the temperature of the ice above its melting temperature of 0°C. Rather, all the heat goes into the change of state. Energy is absorbed during the process of changing ice into water. The water that is produced also remains at 0°C until all of the ice is melted.

### Heats of Fusion and Solidification

All solids absorb heat as they melt to become liquids. The gain of heat in this endothermic process goes into changing the state rather than changing the temperature. The molar heat of fusion of a substance is the heat absorbed by one mole of that substance as it is converted from a solid to a liquid. Since the melting of any substance absorbs heat, it follows that the freezing of any substance releases heat. The molar heat of solidification of a substance is the heat released by one mole of that substance as it is converted from a liquid to a solid. Since fusion and solidification of a given substance are the exact opposite processes, the numerical value of the molar heat of fusion is the same as the numerical value of the molar heat of solidification, but opposite in sign. In other words, . The Figure below shows all of the possible changes of state along with the direction of heat flow during each process.

Figure 17.8

From left to right, heat is absorbed from the surroundings during melting, evaporation, and sublimation. Form right to left, heat is released to the surroundings during freezing, condensation, and deposition.

Every substance has a unique value for its molar heat of fusion, depending on the amount of energy required to disrupt the intermolecular forces present in the solid. When 1 mol of ice at 0°C is converted to 1 mol of liquid water at 0°C, 6.01 kJ of heat are absorbed from the surroundings. When 1 mol of water at 0°C freezes to ice at 0°C, 6.01 kJ of heat are released into the surroundings.

The molar heats of fusion and solidification of a given substance can be used to calculate the heat absorbed or released when various amounts are melted or frozen.

Enjoy the video about the heat of fusion at the link below:

Sample Problem Heat of Fusion

Calculate the heat absorbed when 31.6 g of ice at 0°C is completely melted.

Step 1: List the known quantities and plan the problem .

Known

mass = 31.6 g icemolar mass H 2 O( s ) = 18.02 g/molmolar heat of fusion = 6.01 kJ/mol

Unknown

The mass of ice is first converted to moles. This is then multiplied by the conversion factor that in order to find the kJ of heat absorbed.

Step 2: Solve .

The given quantity is a bit less than 2 moles of ice, and so just less than 12 kJ of heat is absorbed by the melting process.

SummaryMolar heats of fusion and solidification are defined.Calculations of heat changes during fusion and solidification are described.Practice

Work on problems 4-5 at the link below:

http://ths.sps.lane.edu/chemweb/unit4/problems/heatcalc/index.htm

Review

Questions

In the transition from liquid to solid, is energy absorbed or released?In the transition from solid to liquid, is energy absorbed or released?How much energy is released when one mole of water at 0°C changes from liquid to solid?
molar heat of fusion : The heat absorbed by one mole of that substance as it is converted from a solid to a liquid.

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molar heat of solidification : The heat released by one mole of that substance as it is converted from a liquid to a solid.