Carbon tetrafluoride, or tetrafluoromethane, is the most basic fluorocarbon, with really high link strength. That is a colorless, non-flammable gaseous link which drops under the classification of haloalkane (a combination of halogen and alkane). Tetrafluoromethane acts together a advantageous refrigerant, but likewise adds come greenhouse gas contribution in the atmosphere.

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So, is CF4 polar or non-polar? CF4 is a nonpolar molecule. Although all C-F bonds space polar because carbon and fluorine differ in your electronegativity, the in its entirety CF4 molecule is non-polar. This is since of the symmetrical setup of every fluorine atoms roughly the main carbon atom. Thus each separation, personal, instance C-F link dipole cancels out each other causing the net-zero dipole minute of the entire molecule making that nonpolar.

CF4 – Structure, molecular Geometry

The molecule geometry of carbon tetrafluoride is tetrahedral, v the carbon atom at the center, surrounding by four fluorine atoms. However, the CF 4 molecule is arranged in two various planes.

While two C-F bonds lie in the plane of the paper, the various other two perform not. No lone pairs exist in the molecular structure of CF 4 and also the target is that the distance between the Carbon and also Fluorine.

The carbon-fluorine bond length is typically roughly 1.32 Angstrom. The bond angle because that each C-F link is 109°28’, with sp3 hybridization (for the carbon atom).


The Lewis dot structure for CF4 has actually a full of 32 valence electrons, with 7 electrons around each fluorine atom (7×4 = 28) and 4 electrons approximately the main carbon atom.

Each Fluorine atom share one electron about the carbon atom and hence all the octets room completed by share of electron (both Fluorine and also Carbon).

None the less, the sharing of electrons is not equal due to the fact that Fluorine is much an ext electronegative than Carbon (electronegativity of Fluorine = 3.98, while that of Carbon = 2.55).

The lack of lone pair on the central atom offers a tetrahedral molecular form to the molecule of CF4 (according to the VSEPR Theory).

For her reference, I have written a detailed post on CF4 Lewis Structure, Hybridization, and Geometry.

Characteristics of Non-Polar Compounds

The polarity that a link is the cumulative visibility of a non-zero dipole minute in the molecular structure.

Molecules having dipole-dipole interactions have actually a net non-zero dipole minute while those with no dipole-dipole interactions have a dipole minute equal come zero Debye.

Non-polar link are characterized by a variety of factors.

1.) Symmetricity: Molecules v symmetricity in their frameworks tend to have actually a net-zero dipole moment, also if there are dipole pressures existing in individual bonds (between two atoms).

In symmetric molecules, usually, the an outcome of individual dipoles come the end to be equal in magnitude and opposite in their direction.

On this grounds, lock cancel each other out (vector sum = 0) and also hence remove the net dipole moment.

CBr4 is one together compound v the symmetric plan of every C-Br bonds. Below is the write-up to examine out the reason for the non-polarity of CBr4.

2.) Bonding: Hydrogen bonds and covalent bonds room comparatively stronger than weak Vander Waal pressures of attraction.

Compounds through weaker pressures to bind their molecular structures together have a propensity because that being non-polar in nature.

The explanation because that the same is simple. Vander Waal pressures are weak sufficient to be disturbed easily and also contribute to no far-reaching charge amassing at the poles.

Stronger bonds, however, display screen some attractive and repulsive pressures which cause partial fee imbalances.

3.) charge Accumulation: Non-polar molecules are defined by equal sharing of electrons creating a bond. In such a scenario, no partial dues are dispersed on the atoms associated in bond formation.

Without any push or pull on the electrons, the charges are not accumulated or gathered on one of two people pole the the molecule.

Hence, there is no fee gathering in non-polar molecules.

4.) Electronegativity Difference: for a dipole minute to be thought about significant, the difference in the electronegativity of the 2 atoms developing the bond need to be greater than 0.4.

For electronegative differences listed below 0.4, the dipole moment created is as well little. Such short disparities carry out not contribute to the dipole-dipole interactions.

Whereas compounds choose NCl3 having dipole minute 0.6 D is thought about to be slightly polar. Chemistry is full of exceptions. Read out the write-up for the reason for the polarity of NCl3.

However, the is so feasible that separation, personal, instance bonds in a molecule might be polar (due to electronegativity difference), yet the result of all bonds may cancel out.

5.) Properties: Non-polar compounds often tend to have low melting and also boiling points because weaker pressures require less energy to it is in modified.

Why is CF4 a nonpolar compound?

The Dipole minute of C-F bonds

In CF4, each bond has actually its own individual dipole moment.

Because the a substantial difference in the electronegativity of Carbon and also Fluorine, the fluorine atoms often tend to traction the mutual electron pair between C and F towards itself, fashioning one uneven charge distribution and leading come the formation of a dipole moment (with fluorine having a somewhat an adverse charge buildup and carbon left through a partial hopeful charge).


How framework affects the Polarity the CF4?

In CF4, two C-F binding lie in the same aircraft of the molecule, the other two bonds carry out not. However, the result of the 2 bonds comes out to be in the same plane as the two in-plane bonds.

Whereas, the result dipole the the various other two C-F bonds originates precisely 180° to the result of the same airplane bond pairs leading to the cancellation of both the contrary dipoles.

In CF4, the key reason because that the visibility of non-polarity, in spite of the separation, personal, instance bonds being very polar, is the canceling of the dipole moments.


This call-off occurs due to the structural geometry of the molecule the the compound.

Hence, there space no dipole-dipole interaction in the molecule.

How is CF4 produced?

Tetrafluoromethane is formed during a number of processes.

1.) The reaction the graphite Carbon through fluorine leader to the formation of CF4 (Fluorination that Carbon).

C (graphite) + 2F2 (g) ———> CF4 (g)

2.) that can likewise be created by a reaction the CCl2F2 or CCl3F with Hydrogen Fluoride (HF, in gas phase).

CCl2F2 + 2HF (g) ——–> CF4 + 2HClCCl3F + 3HF (g) ——> CF4 + 3HCl

3.) it is a by-product the aluminum processing.

Properties of CF4

Molecular load = 88 g/molBond length = 132.3 pmBond angle = 109°28’Critical temperature = -50.2°CDensity = 3.72 g/LNet dipole moment = 0 DebyeSolubility = soluble in non-polar solvents like benzene and also chloroform and has short solubility in water (about 20 mg/L).Melting point = -183.8°CBoiling suggest = -128°CThe short melting and boiling points of the compound space attributable to its non-polar nature. Non-polar compounds have weaker pressures of attraction which deserve to be agitated through low heat.Carbon tetrafluoride is a colorless, odorless, non-flammable, and also non-explosive gas.It has a middle toxic impact on the person body top top its inhalation.

Uses the CF4

CF4 is specifically popular as a low-temperature refrigerant.It is one inert gas and likewise an oxygen displacer (under standard setting conditions).CF4 is offered in several water etching processes.It has actually several supplies in ghost detectors.It is used in electronic devices microfabrication (either alone or in mix with combination).

Possible greenhouse effects of Tetrafluoromethane

Tetrafluoromethane (CF4) is one exceedingly steady gas, i m sorry is colorless and also non-flammable. It absorbs solid infrared radiation (~ 8 micrometers), and also hence qualified of influencing the greenhouse effect.

The gas has an atmospheric lifetime of around 50,000 years.

It is designated as PFC-14 (perfluorocarbon-14), the most abundant PFC in the atmosphere and its concentration is growing steadily, due to its widespread use as a refrigerant.

Structurally, CF4 is comparable to CFCs (chlorofluorocarbons) but does not include up to the ozone class depletion, because of the lack of chlorine atoms.

In CFCs, the chlorine atoms breakdown upon reacting v UV-rays and lead to exhaustion of O3.

However, in CF4, chlorine is absent and thus no together reactions occur which might weaken the ozone class in the stratosphere.

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C-F bonds room stronger and less most likely to dissociate, and hence make it the many persistent greenhouse gas. It more contributes come long-term an international warming effects.